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maleic anhydride

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108-31-6

C4H2O3

Uses:

Applied to synthesize unsaturated polyester resins, alkyd resins, etc.

 Names and Identifiers

NameMaleic anhydride
SynonymsMA
2,5-FURANDIONE
2,5-Furandione
furan-2,5-dione
MaleicAnhydride
MALIEC ANHYDRIDE
Maleic anhydride
ANHYDRIDE MALEIC
TOXILIC ANHYDRIDE
Sodium n-amylxanthate
cis-Butenedioic anhydride
CAS108-31-6
EINECS203-571-6
InChIInChI=1S/C4H2O3/c5-3-1-2-4(6)7-3/h1-2H
InChIKeyFPYJFEHAWHCUMM-UHFFFAOYSA-N

​Physico-chemical Properties

Molecular FormulaC4H2O3
Molar Mass98.06
Density1.48
Melting Point51-56 °C (lit.)
Boling Point200 °C (lit.)
Flash Point218°F
Water Solubility79 g/100 mL (25 ºC)
Vapor Presure0.16 mm Hg ( 20 °C)
Vapor Density3.4 (vs air)
AppearanceWhite powder
ColorWhite
Exposure LimitNIOSH REL: TWA 1 ppm (0.25 mg/m3), IDLH 10 ppm; OSHA PEL: TWA0.25 ppm; ACGIH TLV: TWA 0.25 ppm with an intended change of 0.1 ppm.
Merck14,5704
BRN106909
pKa0[at 20 ℃]
PH0.8 (550g/l, H2O, 20℃)Hydrolysis
Storage ConditionStore below +30°C.
StabilityStable. Combustible. Incompatible with water, strong oxidizing agents, alkali metals, strong bases, amines, most common metals, polymerization catalysts and accelerators.
SensitiveMoisture Sensitive
Explosive Limit1.4-7.1%(V)
Refractive Index1.4688 (estimate)
Physical and Chemical Propertiescharacter orthorhombic crystal system colorless needle-like or plate-like crystals.
melting point 52.8 ℃
boiling point 202 ℃
relative density 1.480
flash point 110 ℃
soluble in water to produce maleic acid. Dissolve in ethanol and produce esters.
UseIt is used as a raw material for the production of 1, 4-butanediol, γ-butyrolactone, Tetrahydrofuran, succinic acid, unsaturated polyester resin, alkyd resin, etc., and is also used for pharmaceuticals and pesticides

Risk and Safety

Hazard SymbolsC – Corrosive
Risk CodesR22 – Harmful if swallowed
R34 – Causes burns
R42/43 – May cause sensitization by inhalation and skin contact.
Safety DescriptionS22 – Do not breathe dust.
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 – Wear suitable protective clothing, gloves and eye/face protection.
S45 – In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
UN IDsUN 2215 8/PG 3
WGK Germany1
RTECSON3675000
FLUKA BRAND F CODES21
TSCAYes
HS Code2917 14 00
Hazard Class8
Packing GroupIII
ToxicityLD50 orally in Rabbit: 1090 mg/kg LD50 dermal Rabbit 2620 mg/kg

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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