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ALLYL ALCOHOL

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Feature Good stability
Classification Paint Additives
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Acryl Alcohol is a stimulating chemical substance and colorless liquid. It is a chemical substance generated by gas-phase reaction using propylene, acetic acid and oxygen in the presence of fixed-bed catalyst, and can be used as the raw material of many chemical substances.

CategoryDetails
Chemical FormulaCH₂=CHCH₂OH; unsaturated primary alcohol
Key Applications– Glycerine Production: Epichlorohydrin route precursor
– Resins: Epoxy resins, allyl ethers
– Pesticides: Carbamate intermediates
– Pharmaceuticals: Chiral synthesis building block
Physical Properties– Boiling Point: 97°C
– Flash Point: 29°C (closed cup)
– Reactivity: Highly exothermic polymerization potential
– Odor: Pungent, lachrymatory
Safety Hazards– Toxicity: Severe respiratory/dermal irritation
– Carcinogenicity: Suspected (IARC Group 2B)
– Fire Risk: Autoignition at 370°C
– Exposure Limits: ACGIH TLV 0.5ppm (TWA)
Environmental Impact– Water Solubility: Miscible (high mobility in aquatic systems)
– Biodegradation: Readily degrades under aerobic conditions
– Eco-Toxicity: LC50 (fish) = 48mg/L
Handling Precautions– Storage: Cool, ventilated area
– PPE: Chemical-resistant gloves, goggles
– Inhibitors: Requires stabilization against self-polymerization
Market Dynamics– Global Demand: ~25,000 tons/year (2025)
– Growth Drivers: Bio-based glycerine demand, epoxy composites
– Price Drivers: Propylene feedstock costs, supply chain stability
Sustainability Trends– Green Chemistry: Bio-derived production via fermentation
– Process Optimization: Closed-loop reactor systems
– Regulatory Compliance: REACH/TSCA registration updates

Note: Critical intermediate requiring strict temperature control. Emerging focus on bio-based production to reduce environmental footprint.

Physical & Chemical Properties

PropertySpecification
Molecular FormulaC₃H₆O
Boiling Point97°C
Density0.854 g/cm³ (20°C)
Flash Point21°C (closed cup)
SolubilityMiscible with water/organics

Reactivity Profile

Reaction TypeProducts Formed
EsterificationAllyl esters
OxidationGlycerol/acrolein
PolymerizationPoly(allyl alcohol)
EpoxidationGlycidol derivatives

Industrial Applications

 Major Uses

ApplicationFunctionEnd Products
Resin ProductionCrosslinking monomerAllyl resins/diallyl phthalate
Pharmaceutical IntermediatesBuilding blockAntiviral drugs/thyroid meds
AgrochemicalsPrecursorHerbicides/insecticides
Specialty ChemicalsSulfur compound synthesisMustard gas antidotes

Safety & Handling

Hazards: Flammable, toxic (LD50 64 mg/kg oral rat), lachrymator

Protection: Chemical goggles, respirator, butyl rubber gloves

Storage: Nitrogen blanket, <25°C with inhibitor (hydroquinone)

Transport: UN1098 (Class 6.1/3), PG II

Environmental Considerations

Readily biodegradable (BOD5/COD=0.65)

VOC content: 100%

Requires explosion-proof equipment for processing

Conclusion

Allyl alcohol’s unique structure bridges petrochemical and fine chemical industries. While offering valuable synthetic versatility, its toxicity demands rigorous handling protocols. Future applications may expand in bio-based polymer development.

Declaration: The products displayed on this website are intended exclusively for industrial applications or scientific research. They are not intended for medical, pharmaceutical, or food use. In accordance with applicable laws and regulations, purchasing organizations must hold valid qualifications and approvals.

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